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(000000-000000- - 5068) |
Date of Issue: 12/21/2007 12:00:00 AM |
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Supercedes: 12/21/2007 12:00:00 AM |
Chemical Name &
Synonyms: N/A |
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Trade Name &
Synonyms: FREE
W/MOLY AEROSOL |
Chemical Family: Petroleum distillate
mixture |
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Formula is a
mixture: [√] |
Manufacturer Name:
CERTIFIED LABS, DIV. OF NCH
CORP. |
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Manufacturer
Address: BOX 152170
IRVING, TEXAS 75015
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Prepared By: M MCDOWELL/CHEMIST |
Product Code Number: 5068 |
Emergency Phone
Number: 800-424-9300 | |
THE HAZARDS PRESENTED BELOW ARE THOSE OF THE
INDIVIDUAL COMPONENTS |
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Boiling Point (°F): |
160-203
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Specific Gravity
(H20=1): |
0.84
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Vapor Pressure (mm Hg): |
1546
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Color: |
Amber-dark amber
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Vapor Density (Air=1): |
1.7
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Odor: |
Petroleum/vinegar
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pH @ 100% : |
N/A |
Clarity: |
Transparent
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% Volatile by Volume: |
75
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Evaporation Rate (BuAc=1): |
24.8
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H20 Solubility: |
Negligible
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Viscosity: |
Non-Viscous
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Flash Point: |
<80°F |
Method Used: |
Seta-flash
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Flammable Limits: |
Product mixture
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UEL: |
11.5%
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LEL: |
0.5%
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Aerosol Level (NFPA
30B): |
3 | |
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Special Fire Fighting
Procedures:
Firefighters should wear a self-contained breathing
apparatus and full protective gear. Cool fire-exposed
containers with water spray to prevent
bursting. |
Unusual Fire and Explosion
Hazards:
Vapors are heavier than air and may
travel to distant and/or low-lying sources of ignition and
flashback. Product may produce a floating fire hazard as
liquid floats on water. Flame extension is >18 inches,
burnback is >3 inches. Use care as spills may be
slippery. | |
Threshold
Limit Value:
Not Established for Mixture. See Section
II. |
Effects
of Overexposure: |
Acute: (Short Term
Exposure)
EYE CONTACT: Causes irritation seen as stinging, tearing,
redness, and a burning sensation. Prolonged contact may cause
conjunctivitis. SKIN CONTACT: Causes irritation seen as
itching and redness. Product may be absorbed through the skin
in harmful amounts. Injection under the skin, in muscle, or
into the blood stream can cause irritation, inflammation,
swelling, fever, and systemic effects, and mild central
nervous system depression. Injection of pressurized
Hydrocarbons can cause severe, permanent tissue damage.
Initial symptoms may be minor. Prolonged or repeated contact,
as from clothing wet with material, may cause drying,
defatting, and cracking of the skin. INHALATION: May cause
respiratory irritation seen as coughing and sneezing. At low
vapor concentrations, no harmful effects are expected. At high
vapor concentrations, inhalation may cause central nervous
system effects such as headache, dizziness, drowsiness,
weakness, unconciousness, possible anesthetic effects from
central nervous system depression, and may be
fatal. INGESTION: May cause irritation with possible
nausea, vomiting, and diarrhea. May cause central nervous
system effects similar to inhalation. Ingestion and subsequent
vomiting of this product can lead to aspiration of the product
into the lungs which can cause damage and may be
fatal. |
Chronic: (Long Term
Exposure) This product has a
narcotic and Central Nervous System depressive effect. May
cause Kidney and Liver congestion in high concentrations. May
cause anemia, edema, leukocytosis, and a degeneration of the
viscera fats. Prolonged exposure is associated to bronchitis,
hepatic, renal, and cardiac damages, and blood alterations. On
rare occasions, prolonged and repeated exposure to hydrocarbon
or oil mist poses a risk of chronic lung inflammation. This
condition is usually asymptomatic as a result of repeated
small aspirations. Shortness of breath and coughing are the
most common symptoms. Aspiration may lead to pulmonary edema
and hemorrhage, and may be fatal. Signs of lung involvement
include increased respiration and heart rates as well as a
bluish discoloration of the skin. Chronic skin contact may
promote dermatitis and oil acne. In rarer cases, an increased
senstivity to sunlight (photosensitivity) may
occur. Medical conditions aggravated by exposure are
pre-existing respiratory and skin conditions such as asthma,
emphysema, and dermatitis; Pre-existing Blood, Liver,
and Kidney diseases. TARGET ORGANS: Central nervous system,
heart, liver, lungs, and kidneys. The primary routes of
exposure are skin and eye contact. |
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Emergency
First Aid Procedures: |
Inhalation:
Remove from the area to fresh air. Seek medical attention
if respiratory irritation develops or if breathing becomes
difficult. |
Eye Contact:
Rinse the eyes with water. Remove any contact lenses and
continue flushing with plenty of water for several minutes.
Seek medical attention if irritation
develops. |
Skin Contact:
Wash affected areas with large amounts of soap and water
for 15 minutes. Remove contaminated clothing and shoes. Seek
medical attention if irritation persists. Wash clothing and
clean shoes before re-use. |
Ingestion:
Give 3 to 4 glasses of water, but DO NOT induce vomiting.
If vomiting occurs, give fluids again. Get immediate medical
attention. Do not give anything by mouth to an unconscious or
convulsing person. |
Notes to Physician:
Ingestion and subsequent vomiting of this product can lead
to aspiration of the product into the lungs which can cause
damage and may be fatal. Depending on the amount ingested and
retained as well as the toxicity of the product, gastric
lavage should be considered. Keep patient's head below hips to
prevent pulmonary aspiration. If comatose, a cuffed
endotracheal tube will prevent aspiration. In the event of
injection in underlying tissue, immediate treatment should
include extensive incision, debridement and saline irrigation.
Inadequate treatment can result in ischemia and gangrene.
Early symptoms may be
minimal. | |
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ALIPHATIC PETROLEUM
DISTILLATES ORL-RAT LD50: >5,000
mg/kg 3. SKN-RBT LD50:
>3,160 mg/kg 3. IHL-RAT
LC50: >5.2
mg/L/4 hr 5. SKN-RBT:
Moderate irritation
3. EYE-RBT: Mild irritation
3.
Similar
materials were administered orally 5 days/week to male
and female rats at 100, 500 or 1000 mg/kg for 13 weeks. An
additional group was dosed with 100 mg/kg for 13 weeks
followed by a 4-week recovery period. No mortalities or
clinical effects were observed. Liver and kidney weights for
the 500 and 1000 mg/kg exposure groups were significantly
increased. After the 4-week recovery period, there were no
differences in organ weights.
3.
Animal data suggest that slight anemia, adaptive
liver changes, and kidney toxicity may be caused by repeated
overexposure to some similar solvents. The significance of
this to humans is unknown.
3.
Hydrocarbon mists derived from highly refined
petroleum distillates are reported to have low acute and
sub-acute toxicities in animals. Effects from single and
short-term repeated exposures to high concentrations well
above applicable workplace exposure levels include lung
inflammatory reaction, lipoid granuloma formation, and lipoid
pneumonia. In acute and sub-acute studies involving exposures
to lower concentrations at or near current work place exposure
levels produced no significant toxicological effects. In long
term studies (up to two years) no carcinogenic effects have
been reported in any animal species tested. These petroleum
distillates are severely hydrotreated, severely solvent
extracted, and/or processed by mild hydrotreatment and
extraction. For this reason, they are not classified as cancer
hazards. 3.
ETHYL ACETATE
EYE-HMN SDT:
400 ppm
4. IHL-HMN TCLo:
400 ppm
4. ORL-RAT LD50: 5,620
mg/kg
3. IHL-RAT LC50: 16,000
ppm/6h
3. SKN-RBT LD50: >20 mL/kg
4. SKN-RBT LS50:
>18,000
mg/kg
3. INH-RAT
LC50: 200
gm/m3
4.
SODIUM SULFONATE ORL-RAT LD50:
>5,000 mg/kg 3. SKN-RAT
LD50: >2,000 mg/kg
3.
HYDROTREATED
LIGHT NAPHTHENIC PETROLEUM DISTILLATE ORL-RAT
LD50: >5 g/kg 3. SKN-RBT LD50: >3 g/kg 3.
SKN-RBT IRRITATION
<0.5/8.0; no appreciable effect 3. EYE-RBT IRRITATION <15/110; no
appreciable effect 3.
PROPANE IHL-LC50
>40% by volume 4.
N-BUTANE IHL-RAT
LC50: 658 g/m3/4h 3.
Human
volunteers exposed repeatedly to gases of similar hydrocarbon
mixtures ranging from 250 to 1000 ppm exhibited no cardiac or
pulmonary function abnormalities. 3.
SYNTHETIC
ISOPARAFFINIC HYDROCARBON (<3% DMSO
extractables) IHL-RAT LC50: >290 ppm
3. ORL-RAT LD50: >10 g/kg 3. SKN-RBT
LD50: >3 g/kg 3. SKN SENSITIZER: no
3. SKN IRRITATION: slight 3. EYE IRRITATION: slight
3.
This hydrocarbon was administered orally 5 days/week
to male and female rats at 100, 500 or 1000 mg/kg for 13
weeks. An additional group was dosed with 100 mg/kg for 13
weeks followed by a 4-week recovery period. No mortalities or
clinical effects were observed. Liver and kidney weights for
the 500 and 1000 mg/kg exposure groups were significantly
increased. After the 4-week recovery period, there were no
differences in organ weights. 3.
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Incompatibility (Materials to
Avoid):
Strong oxidizing agents such as
Chlorine bleach and concentrated Hydrogen Peroxide;
Chlorosulfonic Acid, Lithium Aluminum Hydride,
2-Chloromethylfuran, Lithium Tetrahydroaluminate, Oleum,
Potassium T-Butoxide, Nitric Acid, Perchloric Acid, Chromium
Trioxide, Chlorosulfonic Acid, Silica Gel, Alumina, Nitrates,
Amines, strong Acids and Bases. |
Hazardous Decomposition
Products:
Oxides of Carbon, Potassium, and, Nitrogen; Aldehydes,
Molybdenum, alkylmercaptans, dialkylsulfides, and Hydrogen
Sulfides. | |
Steps to be Taken if Material is
Released or Spilled:
Due to the nature of the packaging, a large spill is
unlikely. For a small spill, absorb with a damp cloth and
rinse area into a sanitary sewer. Use care as spills may be
slippery. |
Waste Disposal
Method(s):
Dispose of in accordance with all Federal, state, and local
regulations. Typical disposal is to wrap the empty aerosol
container in several layers of newspaper and dispose of in the
trash. Aerosol recycling programs are available in many areas.
Do not puncture or incinerate this container. |
Neutralizing Agent: N/A | |
Required
Ventilation:
Local ventilation is recommended to control exposure from
operations that can generate excessive levels of mists or
vapors. Local ventilation is preferred, because it prevents
dispersion into work areas by controlling it at its
source. |
Respiratory
Protection:
Respirators should be selected by and used under the
direction of a trained health and safety professional
following requirements found in OSHA's respirator standard (29
CFR 1910.134) and ANSI's standard for respiratory protection
(Z88.2-1992). For concentrations above the TLV and/or PEL but
less than 10 times these limits, a NIOSH approved
half-facepiece respirator equipped with appropriate chemical
cartridges may be used. For concentrations greater than 10
times the TLV and/or PEL, consult the NIOSH respirator
decision logic found in publication No. 87-116 or ANSI
Z88.2-1992. |
Glove Protection:
Neoprene or nitrile rubber gloves should be
worn. Ensure compliance with OSHA's personal protective
equipment (PPE) standard for hand protection, 29 CFR
1910.138. |
Eye Protection:
Safety glasses with side shields if the method of
application presents the likelihood of eye contact. Ensure
compliance with OSHA's Personal Protective Equipment (PPE)
standard for eye and face protection, 29 CFR
1910.133. |
Other Protection:
Wear protective clothing when handling. Wash clothing
and clean shoes before re-use. A safety shower and an eyewash
station should be
available. | |
Section X -
Storage and Handling Information
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Precautions to be Taken in Handling
and Storing:
Use with caution around heat, sparks, pilot lights, static
electricity, and open flame. |
Other Precautions:
Keep out of reach of children. Read the entire label before
using the product. Follow the label
directions. | |
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Those
Ingredients listed above are subject to the reporting
requirements of 313 of Title III of the Superfund Amendments
and Reauthorization Act of 1986 and 40 CFR part
372. |
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Please call
1-800-527-9919 for additional information if you are a
California customer. This MSDS is not intended for users in
the state of California. |
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1. Threshold Limit Values for chemical substances and
physical agents and biological exposure indices, ACGIH,
2007. 2. OSHA PEL. 3. Vendor's MSDS. 4.
Registry of toxic effects of chemical substances,
CCINFOWeb, 2007. 5. European Chemical Substances
Information System (ESIS), International Uniform
Chemical Information Database (IUCLID) Chemical Data
Sheets. 6. ChemADVISOR, Inc. Database Release:
2007-4. All the components of this product are in
compliance with the Toxic Substances Control Act (TSCA)
and are either listed on the TSCA inventory or otherwise
exempted from
listing. ----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- IRR:
Irritant, OSHA: Occupational Safety & Health
Administration, IARC: International Agency for the
Research on Cancer, TOX: Toxic, NFPA: National Fire
Protection Association, ppm: Parts Per Million, UEL:
Upper Explosion Limit, STEL: Short-term Exposure Limit,
HMN: Human, mg/m3, IHL: Inhalation, COMB: Combustible,
CORR: Corrosive, MUT: Mutagenic, CARC: Carcinogenic,
N/A: Not Applicable, TLV: Threshold Limit Value, N/E:
Not Established, ORL: Oral, FLAM: Flammable, ASPHYX:
Asphyxiant, C.O.C.: Cleveland Open Cup, PNOR: Particles
Not Otherwise Regulated, LEL: Lower Explosion Limit,
mg/L: Milligrams per Liter, PNOS: Particles Not
Otherwise Specified, g/L: Grams per Liter, PMCC:
Pensky-Martin Closed Cup, NTP: National Toxicology
Program, µg/L: Micrograms per Liter, TCC: Tagliabue
Closed Cup, SEV: Severe, RBT: Rabbit, INV: Intravenous,
ACGIH: American Conference of Governmental Industrial
Hygienists, PEL: Permissible Exposure Limit, MOD:
Moderate, IPT: Intraperitoneal, gm/kg: Grams per
Kilogram, C.C.C.: Cleveland Closed Cup, SKN: Skin,
Milligrams per Cubic Meter, mg/kg: Milligrams per
Kilogram, VOC: Volatile Organic Compound, SDT: Standard
Draize Test, MSE: Mouse, GPG: Guinea
Pig. |
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