MALLINCKRODT INC -- ACETONE -- 6810-01-317-6099
===================== Product Identification ===================== Product ID:ACETONE MSDS Date:04/06/1989 FSC:6810 NIIN:01-317-6099 === Responsible Party === Company Name:MALLINCKRODT INC Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:314-982-5000 Emergency Phone Num:314-982-5000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:ACETONE (SARA III) CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 58.08% OSHA PEL:1000PPM ACGIH TLV:750PPM/1000STEL;9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUPP DATA: IN RCRA APPROVED FACILITY. DO NOT FLUSH TO SEWER! RTECS #:9999999ZZ Ingred Name:OTHER PREC: MATLS. CNTNRS SHD BE BONDED & GROUNDED FOR TRANSFERS TO AVOID STATIC SPARKS. STORAGE & USE AREAS SHD (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: BE NO SMOKING AREAS. USE NON-SPARKING TYPE TOOLS AND EQUIP. CONTACT LENSES SHD NOT BE WORN WHEN WORKING W/MATL. RTECS #:9999999ZZ Ingred Name:VENT: GENERALLY PREFERRED BECAUSE IT CAN CNTRL EMISSIONS OF CONTAM AT ITS SOURCE, PREVENTING DISPERSION OF IT (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: INTO GENERAL WORK AREA. PLEASE REFER TO ACGIH DOCUMENT, "INDUSTRIAL VENTILATION, A MANUAL OF RECOMMENDED (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: PRACTICES", MOST RECENT EDITION, FOR DETAILS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL,RAT) 9750 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL: IRRIT TO NOSE, THROAT, AND MUCOUS MEMBRANES. MAY CAUSE DIZZINESS, DULLNESS, & HEADACHE. NARCOTIC IN HIGH CONC. INGESTION: MAY PRODUCE NARCOTIC EFTS WITH OTHER SYMPTOMS PARALLELING THOSE FROM IN HALATION EXPOSURE. SKIN: IRRITATING DUETO DEFATTING ACTION ON SKIN. MAY CAUSE REDNESS, PAIN, (SEE EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: DRYING AND CRACKING OF SKIN. EYE: VAPORS ARE IRRITATING TO EYES. SPLASHES MAY CAUSE SEVERE IRRITATION, WITH REDNESS AND PAIN. CHRONIC: PROLONGED OR REPEATED SKIN CONTACT MAY PRODUCE SEVERE I RRITATION OR DERMATITIS. Medical Cond Aggravated by Exposure:USE OF ALCOHOLIC BEVERAGES ENHANCES TOXIC EFFECTS. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE O*2. CALL PHYS. INGEST: INDUCE VOMIT IMMED BY GIVING 2 GLASSES OF H*2O & STICKING FINGER DOWN THROAT. NEVER GIVE ANYTH ING BY MOUTH TO UNCON PERSON. CALL PHYSIMMED. SKIN: REMOVE ANY CONTAM CLTHG. WASH SKIN W/SOAP/MILD DETERGENT & H*2O FOR AT LEAST 15 MIN. GET MED ATTN IF IRRIT DEVELOPS/PERSISTS. EYE: WASH (SUP DAT) ===================== Fire Fighting Measures ===================== Flash Point Method:COC Flash Point:-0F,-18C Lower Limits:2.6% Upper Limits:12.8% Extinguishing Media:WATER, DRY CHEMICAL, FOAM OR CARBON DIOXIDE. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA W/FULL FACEPIECE OPER IN PRESS DEMAND/OTHER POSITIVE PRESS MODE & FULL PROT CLTHG. H*2O MAY BE USED TO FLUSH SPILLS AWAY (SUP DATA) Unusual Fire/Explosion Hazard:ABOVE FLASH POINT, VAPOR-AIR MIXTURES ARE EXPLOSIVE WITHIN FLAMMABLE LIMITS NOTED ABOVE. ================== Accidental Release Measures ================== Spill Release Procedures:ISOLATE/ENCLOSE AREA OF LEAK/SPILL. REMOVE ALL SOURCES OF IGNIT. CLEAN-UP PERSONNEL REQ PROT CLTHG & RESP PROT FROM VAPS. CONT & RECOVER LIQ FOR RECLAMATION WHEN POS. LRGR SPILLS & LOT SIZES CAN BE CO LLECTED AS HAZ WASTE & ATOMIZED IN (SUPP DATA) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:DANGER! EXTREMELY FLAM. HARMFUL IF SWALLOWED/INHALED. CAUSES IRRIT. KEEP AWAY FROM HEAT, SPARKS & FLAME. AVOID CONTACT WITH EYES, SKIN & CLOTHING. Other Precautions:KEEP CNTNR CLSD. USE W/ADEQ VENT. AVOID BRTHG VAP. PROT AGAINST PHYS DAMAGE. STORE IN A COOL, DRY WELL-VENT LOCATION, AWAY FROM ANY AREA WHERE FIRE HAZ MAY BE ACUTE. OUTSIDE/DETACHED STORAGE IS PREFER RED. SEPARATE FROM OXIDIZING (ING 3) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF TLV IS EXCEEDED NIOSH/MSHA APPRVD FULL FACEPIECE CHEM CARTRIDGE RESP MAY BE WORN, IN GEN, UP TO MAX USE CONC SPECIFIED BY RESP SUPPLIER. ALTERNATIVELY, A NIOSH/MSHA APPRVD SUP AIR FULL FACEPIECE RE SP/AIRLINED HOOD MAY BE WORN. Ventilation:SYS OF LOCAL &/OR GEN EXHST IS RECOM TO KEEP EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMITS. LOCAL EXHST VENT IS (ING 5) Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:CHEM WORK GOG & FULL LGTH FACESHLD Other Protective Equipment:IMPERVIOUS CLOTHING, INCLUDING BOOTS, LAB COAT, APRON/COVERALLS. EMERGENCY EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC: FROM EXPOS & TO DILUTE SPILLS TO NON-FLAM MIX. FIRST AID PROC: EYES W/PLENTY OF H*2O FOR AT LEAST 15 MIN, LIFTING LOWER & UPPER EYELIDS OCCASIONALLY. GET MED ATTN. IMMED. SPILL PROC: SUITABLE RCRA APPRVD COMBUST CHAMBER/ABSORBED W/VERMICULITE, DRY SAND, EARTH/SIMILAR MATL FOR DISP AS HAZ WASTE (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:134F,57C Melt/Freeze Pt:M.P/F.P Text:-139F,-95C Vapor Pres:400 @ 395C Vapor Density:2.0 Spec Gravity:0.8 Evaporation Rate & Reference:7.7 (BUTYL ACETATE=1) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS, VOLATILE LIQUID. FRAGRANT, MINT-LIKE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING MATERIALS, CHLOROFORM, ALKALIES, ACIDS, POTASSIUM T-BUTOXIDE. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE MAY FORM WHEN HEATED TO DECOMPOSITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:ENSURE COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.