SPECTRUM CHEMICAL MFG. CORP. -- COBALT NITRATE HEXAHYDRATE, C4500, C1315, C1316 -- -
===================== Product Identification ===================== Product ID:COBALT NITRATE HEXAHYDRATE, C4500, C1315, C1316 MSDS Date:09/26/1997 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:SPECTRUM CHEMICAL MFG. CORP. Address:14422 SOUTH SAN PEDRO STREET City:GARDENA State:CA ZIP:90248 Country:US Info Phone Num:310-516-8000 Emergency Phone Num:310-516-8000 Preparer's Name:E. BRULL Chemtrec Ind/Phone:(800)424-9300 CAGE:63415 === Contractor Identification === Company Name:SPECTRUM LABORATORY PRODUCTS INC Address:14422 S SAN PEDRO ST Box:City:GARDENA State:CA ZIP:90248-2027 Country:US Phone:310-516-8000/FAX: 310-516-9843 CAGE:63415 Company Name:SPECTRUM QUALITY PRODUCTS, INC. Address:14422 SOUTH SAN PEDRO STREET Box:City:GARDENA State:CA ZIP:90248 Country:US Phone:(310) 516-8000 CAGE:TO829 ============= Composition/Information on Ingredients ============= Ingred Name:COBALT NITRATE HEXAHYDRATE CAS:10026-22-9 RTECS #:QU7355500 = Wt:100. ACGIH TLV:0.02 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL (LD50): ACUTE: 691 MG/KG (RAT) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:POTENTIAL ACUTE HEALTH EFFECTS: NO SPECIFIC INFORMATION IS AVAILABLE IN OUR DATABASE REGARDING THE OTHER TOXIC EFFECTS OF THIS MATERIAL FOR HUMANS. THE PRODUCT IS A SEVERE EYE IRRITANT. PROLONGED EXPO SURE MAY RESULT IN SKIN BURNS AND ULCERATIONS. OVEREXPOSURE BY INHALATION MAY CAUSE RESPIRATORY IRRITATION. POTENTIAL CHRONIC HEALTH EFFECTS: CARCINOGENIC EFFECTS: NOT AVAILABLE, MUTAGENIC EFFECTS: NO T AVAILABLE, TERATOGENIC EFFECTS: NOT AVAILABLE,TOXICITY OF THIS PRODUCT TO THE REPRODUCTIVE SYSTEM: NOT AVAILABLE. THERE IS NO KNOWN EFFECT FROM CHRONIC EXPOSURE TO THIS PRODUCT. Explanation of Carcinogenicity:IARC CANCER REVIEW:GROUP 2B VOLUME (ISSUE) 52, PAGE 363, 1991. Medical Cond Aggravated by Exposure:REPEATED OR PROLONGED EXPOSURE IS NOT KNOWN TO AGGRAVATE MEDICAL CONDITION. ======================= First Aid Measures ======================= First Aid:EYE CONTACT: IMMEDIATELY FLUSH EYES WITH RUNNING WATER FOR AT LEAST 15 MINUTES, KEEPING EYELIDS OPEN. COLD WATER MAY BE USED. SKIN CONTACT: NO KNOWN EFFECT ACCORDING TO OUR DATABASE. SERIOUS SKIN CON TACT: NO ADDITIONAL INFORMATION. INHALATION: ALLOW THE VICTIM TO REST IN A WELL VENTILATED AREA. SEEK IMMEDIATE MEDICAL ATTENTION. SERIOUS INHALATION: EVACUATE THE VICTIM TO A SAFE AREA AS SOON AS PO SSIBLE. LOOSEN TIGHT CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF THE VICTIM IS NOT BREATHING, PERFORM MOUTH-TO-MOUTH RESUSCITATION. WARNING: IT MAY BE DANGEROUS TO (OTHER INFORMATION) ===================== Fire Fighting Measures ===================== Lower Limits:NOT APPLIC Upper Limits:NOT APPLIC Extinguishing Media:FIRE FIGHTING MEDIA AND INSTRUCTIONS: NON-FLAMMABLE. USE MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH-APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . FLAMMABILITY OF THE PRODUCT: NON-FLAMMABLE. PRODUCTS OF COMBUSTION: NOT APPLICABLE. FIRE HAZARDS IN PRESENCE OF OTHER SUBSTANCES: NOT APP LICABLE. SPECIAL REMARKS ON FIRE HAZARDS: NO ADDITIONAL REMARK. SPECIAL REMARKS ON EXPLOSION HAZARDS: NO ADD REMARK. Unusual Fire/Explosion Hazard:EXPLOSION HAZARDS: RISKS OF EXPLOSION OF PRODUCT IN PRESENCE OF MECHANICAL IMPACT: NOT AVAILABLE. RISK OF EXPLOSION OF THE PRODUCT TN PRESENCE OF STATIC DISCHARGE: NOT AVAILABLE. NO SPECIFIC INFORMA TION IS AVAILABLE IN OUR DATABASE REGARDING THE PRODUCT'S RISKS OF EXPLOSION IN THE PRESENCE OF VARIOUS MATERIALS. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILL: USE APPROPRIATE TOOLS TO PUT SPILLED SOLID IN CONVENIENT WASTE DISPOSAL CONTAINER. LARGE SPILL: OXIDIZING MATERIAL. STOP LEAK IF WITHOUT RISK. AVOID CONTACT WITH COMBUSTIBLE MATERIAL (WOO D, PAPER, OIL, CLOTHING...). KEEP SUBSTANCE DAMP USING WATER SPRAY. DO NOT TOUCH SPILLED MATERIAL. PREVENT ENTRY INTO SEWERS, BASEMENTS OR CONFINED AREAS; DIKE IF NEEDED. (NEUTRALIZING AGENT) Neutralizing Agent:N/P. SPILL RELEASE PROCEDURES (CONT): CALL FOR ASSISTANCE ON DISPOSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORAGE: OXIDIZING MATERIALS SHOULD BE STORED IN A SEPARATE SAFETY STORAGE CABINET OR ROOM. PRECAUTIONS: KEEP FROM HEAT. KEEP AWAY FROM SOURCES OF IGNITION. KEEP AEAY FROM COMBUSTIBLE MATERIALSLS. DO NOT INGEST. DO NOT BREATHE DUST. WEAR SUITABLE PROTECTIVE CLOTHING. IF INGESTED,(OTHER PRECAUTIONS) Other Precautions:N/P. HANDLING AND STORAGE PRECAUTIONS (CONT): SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THE CONTAINER OR THE LABEL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST RESPIRATOR. BE SURE TO USE A NIOSH APPROVED RESPIRATOR OR EQUIVALENT. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. IN CASE OF A LARGE SPILL: A SELF CONTAINED BREATHING APPARATUS ( NIOSH APPROVED - ) SHOULD BE USED TO AVOID INHALATION OF THE PRODUCT. Ventilation:USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO KEEP AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. (SUPP SAFETY & HLTH) Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:SAFETY GLASSES (ANSI APPROVED - ). Other Protective Equipment:LAB COAT. EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . PERSONAL PROTECTION IN CASE OF A LARGE SPILL: SPLASH GOGGLES. FULL SUIT. DUST RESPIRATOR. BOOTS. GLOVES. (WORK HYGENIC PRACTICES) Work Hygienic Practices:N/P. OTHER PROTECTIVE EQUIPMENT (CONT): SUGGESTED PROTECTIVE CLOTHING MIGHT NOT BE SUFFICIENT; CONSULT A SPECIALIST BEFORE HANDLING THIS PRODUCT. Supplemental Safety and Health VENTILATION (CONT): IF USER OPERATIOND GENERATE DUST, FUME OR MIST, USE VENTILATION TO KEEP EXPOSURE TO AIRBORNE CONTAMINENTS BELOW THE EXPOSURE LIMIT. EXPOSURE LIMITS: TWA: 0.02 MG/M3 FROM ACGIH (19 95). CONSULT LOCAL AUTHORITIES FOR ACCEPTABLE EXPOSURE LIMITS. ================== Physical/Chemical Properties ================== Boiling Pt:=74.C, 165.2F B.P. Text:DECOMPOSES Melt/Freeze Pt:=56.C, 132.8F Decomp Temp:=74.C, 165.2F Vapor Pres:NOT AVAILABLE Vapor Density:NOT AVAILA Spec Gravity:1.88 (WATER=1) pH:NOT AVAILABLE Solubility in Water:EASILY; IN HOT OR COLD Appearance and Odor:SOLID; ODOR: NOT AVAILABLE, TASTE: NOT AVAILABLE, COLOR: NOT AVAILABLE. Percent Volatiles by Volume:NOT AVAILABL ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NO SPECIFIC INFORMATION IS AVAILABLE IN OUR DATABASE REGARDING THE REACTIVITY OR CORROSIVITY OF THIS MATERIAL IN PRESENCE OF VARIOUS OTHER MATERIALS. Stability Condition to Avoid:THE PRODUCT IS STABLE. INSTABILITY TEMPERATURE: NOT AVAILABLE. CONDITIONS OF INSTABILITY: NO ADDITIONAL REMARK. Hazardous Decomposition Products:SPECIAL REMARKS ON REACTIVITY: NO ADDITIONAL RECORROSIVITY: NO ADDITIONAL REMARK. SPECIAL REMARKS ON CORROSIVITY: NO ADDITIONAL REMARK. =================== Toxicological Information =================== Toxicological Information:TOXICITY TO ANIMALS: ACUTE ORAL TOXICITY (LD50): 691 MG/KG (RAT). CHRONIC EFFECTS ON HUMANS: TOXICITY OF PRODUCT TO REPRODUCTIVE SYSTEM: NOT AVAILABLE. OTHER TOXIC EFFECTS ON HUMANS: NO SPECIFIC INFOR MATION IS AVAILABLE REGARDING THE OTHER TOXIC EFFECTS OF THIS MATERIAL FOR HUMANS. SPECIAL REMARKS ON TOXICITY TO HUMANS: NO ADDITIONAL REMARK. SPECIAL REMARKS ON CHRONIC EFFECTS ON HUMANS: NO ADDITI ONAL REMARK. SPECIAL REMARKS ON OTHER TOX EFFECTS ON HUMANS: NO ADDITIONAL REMARK. ===================== Ecological Information ===================== Ecological:ECOTOXICITY: NOT AVAILABLE. BOD5 AND COD: NOT AVAILABLE. PRODUCTS OF BIODEGRADATION: SOME METALLIC OXIDES. TOXICITY OF PRODUCTS OF BIODEGRADATION: THE PRODUCTS OF DEGRADATION ARE LESS TOXIC THAN PRO DUCT ITSELF. SPECIAL REMARKS ON PRODUCTS OF BIODEGRADATION: NO ADDITIONAL REMARK. PHYSICAL AND CHEMICAL PROPERTIES (CONT): MOLECULAR WEIGHT: 291.03. CRITICAL TEMPERATURE: NOT AVAILABLE. VOLATILIT Y: NOT AVAILABLE. ODOR THRESHOLD: NOT AVAILABLE. WATER/OIL DIST. COEFF.: NOT AVAILABLE. IONICITY (IN WATER): NOT AVAILABLE. DISPERSION PROPERTIES: SEE SOLUBILITY IN WATER. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECYCLE TO PROCESS, IF POSSIBLE. CONSULT YOUR LOCAL OR REGIONAL AUTHORITIES. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE & LOCAL REGULATIONS . =================== MSDS Transport Information =================== Transport Information:D.O.T. CLASSIFICATION: DOT CLASS 5.1 OXIDIZER. IDENTIFICATION: NITRATE, INORGANIC, N.O.S. (COBALT NITRATE) UN1477, III. SPECIAL PROVISIONS FOR TRANSPORT: MARINE POLLUTANT. D.O.T. [PICTOGRAMS]. OT HER INFO (CONT): BETWEEN THE VICTIM'S TEETH. HAVE A CONSCIOUS PERSON DRINK SEVERAL GLASSES OF WATER OR MILK. INDUCE VOMITING BY STICKING FINGER IN THROUT. SEEK IMMEDIATE MEDICAL ATTENTION. SERIOUS IN GESTION: EXAMINE THE LIPS AND MOUTH TO ASCERTAIN WHETHER THE TISSUES ARE DAMAGED, A POSSIBLE INDICATION THAT THE TOXIC MATERIAL WAS INGESTED;THE ABSENCE OF SUCH SIGNS, HOWEVER, IS NOT CONCLUSIVE. REMO VE DENTURES IF ANY. WATCH (SARA III) ===================== Regulatory Information ===================== SARA Title III Information:FOLLOWING PRODUCT LISTED BY SARA 313; COBALT NITRATE HEXAHYDRATE. TRANSPORT INFO (CONT): FOR AN OBSTRUCTION IN THE VICTIM'S MOUTH. REMOVE IF POSSIBLE WHAT IS CAUSING THE OBSTRUCTION BUT DO NOT FORCE FINGERS OR A HARD OBJECT BETWEEN THE VICTIM'S TEETH. IF A SOFT PAD CAN BE INSERTED BETWEEN THE VICTIM'S TEETH, IT WILL PROTECT THE TONGUE FROM BEING BITTEN. A BADLY BLEEDING TONGUE IMMENSELY COMPLICA TES THE PATIENT'S PROBLEMS. HAVE CONSCIOUS PERSON DRINK SEVERAL GLASSES OF WATER OR MILK. INDUCE VOMITING BY STICKING FINGER IN THROAT. LOWER THE HEAD SO THE VOMIT WILL NOT REENTER THE MOUTH AND THROA T. IF CONVULSIONS OCCUR, (STATE REGS) Federal Regulatory Information:OSHA: HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200. WHMIS (CANADA): WHMIS CLASS C - OXIDIZING MATERIAL. WHMIS CLASS D-2A - MATERIAL CAUSING OTHER TOXIC EFFECTS (VERY TOXI C). DSCL (EEC): R8 - CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE. R9 - EXPLOSIVE WHEN MIXED WITH COMBUSTIBLE MATERIAL. R22: HARMFUL IF INGESTED. HMIS (USA): HEALTH-1, FIRE-0, REACTIVITY-0. NA TIONAL FIRE PROTECTION ASSOCIATION (USA): HEALTH = 1, FLAMMABILITY = 0, REACTIVITY = 0, SPECIFIC HAZ ARD = OXY. WHMIS (CANADA), DSCL (EUROPE), TDG (CANADA), ADR (EUROPE): PICTOGRAMS. State Regulatory Information:CALIFORNIA PROPOSITION 65 WARNINGS: WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. CHEMICAL INGREDIENT(S) REQUIRING T HIS WARNING: NONE. THE FOLLOWING PRODUCT(S) IS (ARE) LISTED BY THE STATES OF PENNSYLVANIA AND MASSACHUSETTS: COBALT NITRATE HEXAHYDRATE. SARA III (CONT): DO NOT RESTRAIN, BUT REMOVE OBJECTS WHICH M IGHT INJURE VICTIM OR ORIENT VICTIM TO PREVENT HIM (HER) FROM STRIKING FIXED HEAVY OBJECTS. IF CONVU LSIONS CEASE, TURN THE VICTIM ON THE SIDE OR FACE DOWN SO THAT ANY FLUID IN THE MOUTH WILL DRAIN. SEEK MEDICAL ATTENTION. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.