FARMLAND INDUSTRIES, INC -- GASOLINE, UNLEADED (ALL GRADES) -- 9130-01-282-2844
===================== Product Identification ===================== Product ID:GASOLINE, UNLEADED (ALL GRADES) MSDS Date:02/21/1991 FSC:9130 NIIN:01-282-2844 === Responsible Party === Company Name:FARMLAND INDUSTRIES, INC Address:PETROLEUM DIVISION Box:7305 City:KANSAS CITY State:MO ZIP:64116 Country:US Info Phone Num:816-459-4100 Emergency Phone Num:816-459-4100 OR 316-251-4000 Preparer's Name:DAVID R. SCHONAUER CAGE:6G072 === Contractor Identification === Company Name:FARMLAND INDUSTRIES,INC.,BULK PERTOLEUM PROD DIV. Box:7305 City:KANSAS CITY State:MO ZIP:64116-0005 Country:US Phone:316-251-4000, CHEMTREC 800-424-9300 CAGE:6G072 ============= Composition/Information on Ingredients ============= Ingred Name:GASOLINE - PRODUCT MIXTURE CONTAINING THE FOLLOWING INGREDIENTS:CAS:8006-61-9 RTECS #:LX3300000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM/500 STEL ACGIH TLV:300 PPM/500STEL;9293 Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <20% Other REC Limits:NONE RECOMMENDED OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: <20% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: <6% Other REC Limits:NONE RECOMMENDED OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA III) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9293 Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: <3% Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM/125 STEL ACGIH TLV:100 PPM/125STEL 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS >5G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:INHALATION: MODERATE RISK OF VAPOR INTOXICATION. MAJOR RISK IS ENCLOSED SPACES WITH POOR VENTILATION. SKIN: DEFATTING WITH DRYING AND CRACKING CAN LEAD TO DERMATITIS AND SECONDARY INFECTION. EYE: IRRI TANT. INGESTION: BURNING OF MOUTH AND UPPER GI TRACT, VOMITING AND DIARRHEA. PROLONGED OR REPEATED CONTACT: DERMATITIS. Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:INHALATION MAY CAUSE EUPHORIA, LUNG IRRITATION AND EDEMA, HEADACHE, DIZZINESS, DROWSINESS, CONVULSIONS, COMA, CYANOSIS, GENERALIZED DEPRESSION. INGESTION MAY CAUSE GENERAL DEPRESSION, SEDATION, RESPIR ATORY DEPRESSION, COMA. Medical Cond Aggravated by Exposure:MAY AGGRAVATE PRE-EXISTING DERMATITIS, RESPIRATORY ILLNESS, OR OTHER CONDITIONS WHICH HAVE THE SAME SYMPTOMS OR EFFECTS AS STATED ABOVE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. FOR RESPIRATORY DISTRESS, GIVE AIR, OXYGEN, OR CPR IF NECESSARY. INGESTION: DO NOT INDUCE VOMITING. KEEP HEAD BELOW HIPS IF VOMITING OCCURS TO PREVENT ASPIRATION INTO LUNGS. GET MEDICAL ATTENTION IF REQUIRED IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:-40F,-40C Lower Limits:1.4 Upper Limits:7.6 Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. Fire Fighting Procedures:WATER MAY BE INEFFECTIVE ON FLAMES, BUT SHOULD BE USED TO KEEP FIRE-EXPOSED CONTAINERS COOL. LARGE FIRES, SUCH AS TANK FIRES, SHOULD BE FOUGHT WITH CAUTION. Unusual Fire/Explosion Hazard:HIGHLY VOLATILE MATERIAL. FLOWING GASOLINE CAN BE IGNITED BY SELF-GENERATED STATIC ELECTRICITY. VAPORS MAY TRAVEL ALONG THE GROUND TO A REMOTE IGNITION SOURCE. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL: TAKE UP WITH NON COMBUSTIBLE ABSORBENT SUCH AS FULLERS EARTH OR SAND. PLACE INTO CONTAINERS FOR LATER DISPOSAL. LARGE: CONTAIN SPILL IN EARTHEN DIKES FOR LATER RECOVERY. CONTROL IGNITION SOURCE S AROUND SPILL AREA. REPORT SPILLS AS REQUIRED. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID STATIC IGNITION HAZARD WHEN TRANSFERRING MATERIAL. KEEP CONTAINERS CLOSED AND AWAY FROM HEAT & IGNITION SOURCES! DO NOT USE AS CLEANING AGENT. Other Precautions:EMPTY CONTAINERS RETAIN SOME LIQUID/VAPOR RESIDUES; HAZARD PRECAUTIONS MUST BE OBSERVED WHEN HANDLING EMPTIES. KEEP OUT OF REACH OF CHILDREN! DO NOT USE ANY HYDROCARBON FUEL IN SPACES WITHOUT ADEQUATE VENTILATION. USE ONLY AS A FUEL. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR, SUPPLIED AIR, OR SELF-CONTAINED BREATHING APPARATUS (SCBA) MUST BE USED WHEN VAPOR CONCENTRATIONS EXCEED THE OCCUPATIONAL EXPOSURE LIMITS. Ventilation:USE ADEQUATE VENTILATION TO KEEP VAPOR CONCENTRATIONS OF THIS MATERIAL BELOW THE OCCUPATIONAL EXPOSURE LIMITS. Protective Gloves:WEAR OIL IMPERVIOUS (EG: NITRILE) GLOVES Eye Protection:USE CHEMICAL SAFETY GOGGLES & FACESHIELD Other Protective Equipment:OIL IMPERVIOUS INDUSTRIAL WORK CLOTHING TO MINIMIZE SKIN CONTACT. EYE BATH AND SAFETY SHOWER RECOMMENDED. Work Hygienic Practices:USE GOOD PERSONAL HYGIENE. USE WATERLESS HAND CLEANER TO WASH EXPOSED SKIN. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health THE VARIABLE COMPOSITION MAKES IT IMPOSSIBLE TO SET A SPECIFIC EXPOSURE LIMIT FOR ALL COMPOSITIONS OF THIS MATERIAL. SPECIFIC EXPOSURE LIMITS FOR POTENTIAL COMPONENTS SUCH AS BENZENE SHOULD BE APPLIED BASED ON AIR MONITORING TO ASSURE EMPLOYEES ARE NOT EXPOSED TO EXCESSIVE VAPOR LEVELS OF COMPONENTS. ================== Physical/Chemical Properties ================== HCC:F1 Boiling Pt:=26.7C, 80.F Vapor Pres:400 Vapor Density:4 Spec Gravity:0.72 Evaporation Rate & Reference:SLOWER THAN ETHER Solubility in Water:NEGLIGIBLE Appearance and Odor:REDDISH GOLDEN BROWN LIQUID WITH GASOLINE ODOR. Percent Volatiles by Volume:>95 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION Hazardous Decomposition Products:BURNING OR EXCESSIVE HEATING MAY PRODUCE CARBON MONOXIDE AND OTHER HARMFUL GASES/VAPORS. ==================== Disposal Considerations ==================== Waste Disposal Methods:IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE IF THE MATERIAL IS A HAZARDOUS WASTE AT THE TIME OF DISPOSAL. CHECK BEFORE DISPOSING TO BE SURE YOU ARE IN COMPLIANCE WITH ALL APPLICABLE LAWS AND REG ULATIONS. CHEMTREC/RCRA EMER. NO.:800-424-9346 Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.